Some tips on 14678-05-8

14678-05-8 Isoxazol-5-amine 84591, aIsoxazoles compound, is more and more widely used in various.

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.14678-05-8,Isoxazol-5-amine,as a common compound, the synthetic route is as follows.

Example 37 Synthesis of ethyl 2-(2,4,5-trifluorobenzoyl)-3-(isoxazol-5-ylamino)acrylate (Compound No. 87) Ethyl 2,4,5-trifluorobenzoylacetate (1.50 g), 1.36 g of ethyl orthoformate and 2.80 g of acetic anhydride were combined, followed by heating at 130C for 3 hours. Excess ethyl orthoformate and acetic anhydride were distilled off. The residue was dissolved in 30 ml of chloroform. To the resulting solution, a solution of 512 mg of 5-aminoisoxazole in 30 ml of methanol was added, followed by stirring at room temperature for 3 hours. The solvent was distilled off. The residue was purified using a silica gel column (hexane:chloroform = 1:1), whereby 1.74 g of the title compound was obtained as a colorless solid.

14678-05-8 Isoxazol-5-amine 84591, aIsoxazoles compound, is more and more widely used in various.

Reference£º
Patent; WAKUNAGA SEIYAKU KABUSHIKI KAISHA; FUJISAWA PHARMACEUTICAL CO., LTD.; EP700912; (1996); A1;,
Isoxazole – Wikipedia
Isoxazole | C3H3NO – PubChem