Extracurricular laboratory: Synthetic route of 676-96-0

This literature about this compound(676-96-0)Recommanded Product: 676-96-0has given us a lot of inspiration, and I hope that the research on this compound(Trimethylphosphineoxide) can be further advanced. Maybe we can get more compounds in a similar way.

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 676-96-0, is researched, SMILESS is CP(C)(C)=O, Molecular C3H9OPJournal, Article, Angewandte Chemie, International Edition called Silylated Sulfuric Acid: Preparation of a Tris(trimethylsilyl)oxosulfonium [(Me3Si-O)3SO]+ Salt, Author is Blasing, Kevin; Labbow, Rene; Schulz, Axel; Villinger, Alexander, the main research direction is silylated sulfuric acid reactivity; crystal structure mol tristrimethylsilyl oxosulfonium salt derivative preparation optimized; Lewis acid; silylium ion; structure; sulfate; synthesis.Recommanded Product: 676-96-0.

The chem. of silylated sulfuric acid, O2S(OSiMe3)2 (T2SO4, T=Me3Si; also known as bis(trimethylsilyl) sulfate), has been studied in detail with the aim of synthesizing the formal autosilylation products of silylated sulfuric acid, [T3SO4]+ and [TSO4]-, in analogy to the known protonated species, [H3SO4]+ and [HSO4]-. The synthesis of the [TSO4]- ion only succeeds when a base, such as OPMe3 that forms a weakly coordinating cation upon silylation, is reacted with T2SO4, resulting in the formation of [Me3POT]+[TSO4]-. [T3SO4]+ salts could be isolated starting from T2SO4 in the reaction with [T-H-T]+[B(C6F5)4]- or T+[CHB11Br6H5]- when a weakly coordinating anion is used as counterion. All silylated compounds could be crystallized and structurally characterized.

This literature about this compound(676-96-0)Recommanded Product: 676-96-0has given us a lot of inspiration, and I hope that the research on this compound(Trimethylphosphineoxide) can be further advanced. Maybe we can get more compounds in a similar way.

Reference:
Isoxazole – Wikipedia,
Isoxazole | C3H3NO – PubChem