The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 2-Chloropyridine 1-oxide(SMILESS: ClC1=CC=CC=[N+]1[O-],cas:2402-95-1) is researched.Name: Trimethylphosphineoxide. The article 《The oxidation of pyridine and alcohol using the Keggin-type lacunary polytungstophosphate as a temperature-controlled phase transfer catalyst》 in relation to this compound, is published in Journal of Molecular Catalysis A: Chemical. Let’s take a look at the latest research on this compound (cas:2402-95-1).
A novel temperature-controlled phase transfer catalyst of [(C18H37)2(CH3)2N]7[PW11O39] has been developed for the oxidation of pyridines and alcs. with hydrogen peroxide. The reactions were conducted in 1,4-dioxane, and high yields of the corresponding heterocyclic N-oxides and ketones were obtained under relative mild conditions. The catalyst could be easily recovered and reused after reaction with cooling. There was no discernable loss in activity and selectivity after several reaction cycles.
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Reference:
Isoxazole – Wikipedia,
Isoxazole | C3H3NO – PubChem