Fun Route: New Discovery of 2402-95-1

Compound(2402-95-1)COA of Formula: C5H4ClNO received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(2-Chloropyridine 1-oxide), if you are interested, you can check out my other related articles.

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Two cobalt monophosphonates: Syntheses, structures and magnetic properties, published in 2013-09-01, which mentions a compound: 2402-95-1, mainly applied to hydrothermal preparation crystal structure magnetic property cobalt hydroxypyridinephosphonate complex, COA of Formula: C5H4ClNO.

Hydrolysis of di-Et 6-chloro-2-pyridinephosphonate in HCl solution affords 6-hydroxy-2-pyridinephosphonic acid (H2hppa 1). In the structure, extensive hydrogen bonding interactions link the phosphonic acid mols. into a two-dimensional network. Reactions of H2hppa and cobalt acetate under hydrothermal conditions result in a new cobalt phosphonate Co(hppa)(H2O) (2). Compound 2 shows a layer structure, in which {Co2O2} dimers are connected through the corner-sharing of {CoO5N} octahedra and {PO3C} tetrahedra, forming an inorganic double-layer. Introduction of a second ligand (1,4-bis(imidazol-1-ylmethyl)benzene, L (8)) in the reaction system, compound [Co(hppa)(L)0.5(H2O)]·H2O (3) was obtained. In this structure, Co2+ ions are bridged by O-P-O bridges into an inorganic layer and the layers are pillared up by 1,4-bis(imidazol-1-ylmethyl)benzene. Magnetic study suggests that the existence of weak ferromagnetic coupling between Co2+ ions in the {Co2O2} unit for 2. For compound 3, O-P-O bridges mediate very weak antiferromagnetic interactions.

Compound(2402-95-1)COA of Formula: C5H4ClNO received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(2-Chloropyridine 1-oxide), if you are interested, you can check out my other related articles.

Reference:
Isoxazole – Wikipedia,
Isoxazole | C3H3NO – PubChem