Final Thoughts on Chemistry for 5-Methylisoxazol-3-amine

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Thiomethylation of heteroaromatic amines with formaldehyde-hydrogen sulfide gave linear and cyclic heteroatom compounds: N,N?- [methylenebis(sulfanediylmethylene)]bishetarenamines and 5-hetaryl-1,3,5- dithiazinanes. N,N?-[Methylenebis(sulfanediylmethylene)]bishetarenamines were found to undergo transformation into 5-hetaryl-1,3,5-dithiazinanes by the action of CH2O-H2S. Transamination of 5-methyl-1H-pyrazol- 3-amine, 6-nitro-1,3-benzothiazol-2-amine, and 5-bromopyridin-2-amine with 5-methyl-1,3,5-dithiazinane selectively afforded the corresponding 5-hetaryl-1,3,5-dithiazinanes. Pleiades Publishing, Ltd., 2011.

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Reference：
Isoxazole – Wikipedia,
Isoxazole | C3H3NO – PubChem