Xu, Shiyang’s team published research in Organic Letters in 20 | CAS: 57103-14-7

Organic Letters published new progress about 57103-14-7. 57103-14-7 belongs to isoxazole, auxiliary class Fused Tricycles,Carbazoles, name is 9-(4-Fluorophenyl)-9H-carbazole, and the molecular formula is C14H12N2S, COA of Formula: C18H12FN.

Xu, Shiyang published the artcileRh(III)-Catalyzed C-H Activation of Boronic Acid with Aryl Azide, COA of Formula: C18H12FN, the publication is Organic Letters (2018), 20(18), 5578-5582, database is CAplus and MEDLINE.

A Rh(III)-catalyzed C-H activation of boronic acid with aryl azide to obtain unsym. carbazoles, 1H-indoles, or indolines has been developed. The reaction constructs dual distinct C-N bonds via sp2/sp3 C-H activation and rhodium nitrene insertion. Synthetically, this approach represents an access to widely used carbazole derivatives The practical application to CBP and unsym. TCTA derivatives has also been performed. Mechanistic experiments and DFT calculations demonstrate that a five-membered rhodacycle species is the key intermediate.

Organic Letters published new progress about 57103-14-7. 57103-14-7 belongs to isoxazole, auxiliary class Fused Tricycles,Carbazoles, name is 9-(4-Fluorophenyl)-9H-carbazole, and the molecular formula is C14H12N2S, COA of Formula: C18H12FN.

Referemce:
https://en.wikipedia.org/wiki/Isoxazole,
Isoxazole | C3H3NO – PubChem