Product Details of 2402-95-1. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 2-Chloropyridine 1-oxide, is researched, Molecular C5H4ClNO, CAS is 2402-95-1, about Heteroarene Phosphinylalkylation via a Catalytic, Polarity-Reversing Radical Cascade. Author is Buquoi, J. Quentin; Lear, Jeremy M.; Gu, Xin; Nagib, David A..
A polarity-reversing radical cascade strategy for alkene difunctionalization by vicinal C-C and C-P bond formation has been developed. This approach to concurrently adding phosphorus and a heteroarene across an olefin is enabled by photocatalytic generation of electrophilic P-centered radicals. Upon chemoselective addition to an olefin, the resulting nucleophilic C-centered radical selectively combines with electrophilic heteroarenes, such as pyridines. This multicomponent coupling scheme for phosphinylalkylation complements classic two-component methods for hydrophosphinylation of alkenes and C-H phosphinylation of arenes. Included competition and photoquenching experiments provide insight into the selectivity and mechanism of this polarity-reversal pathway.
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Reference:
Isoxazole – Wikipedia,
Isoxazole | C3H3NO – PubChem