Cheisson, Thibault; Cole, Bren E.; Manor, Brian C.; Carroll, Patrick J.; Schelter, Eric J. published an article about the compound: Trimethylphosphineoxide( cas:676-96-0,SMILESS:CP(C)(C)=O ).Safety of Trimethylphosphineoxide. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:676-96-0) through the article.
Phosphoryl ligands of the general formula O:PR3 (R = Me, OMe, Et, nBu, Ph, iPr, NMe2) were coordinated to [Nd(TriNOx)] (TriNOx3- = [(2-tBuNO)C6H4CH2]3N)3- and characterized. Solution equilibrium constants for each complex were determined, demonstrating a large range for phosphoryl ligands Lewis basicity. Thermogravimetric analyses provided evidence for the qual. thermodn. preference of phosphoryl ligands for [Nd(TriNOx)] over the dysprosium analog. These findings were exploited for the separation of binary mixtures of neodymium/dysprosium and lanthanum/neodymium. Implementation of phosphoryl ligands in the TriNOx separation system expands its scope and demonstrates a fundamentally different mode for separating rare-earth cations based on adducts with neutral donors.
From this literature《Phosphoryl-Ligand Adducts of Rare Earth-TriNOx Complexes: Systematic Studies and Implications for Separations Chemistry》,we know some information about this compound(676-96-0)Safety of Trimethylphosphineoxide, but this is not all information, there are many literatures related to this compound(676-96-0).
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