Chemistry is traditionally divided into organic and inorganic chemistry. Product Details of 1072-67-9, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent，Which mentioned a new discovery about 1072-67-9
Reaction of [Ln(CH2SiMe3)3(thf) 2] (Ln = Y, Yb, and Lu) with one equivalent of Me 2Si(C5Me4H)NHR? (R? = Ph, 2,4,6-Me3C6H2) affords straightforwardly the corresponding half-sandwich rare-earth metal alkyl complexes [{Me 2Si(C5Me4)(NR?)}Ln(CH 2SiMe3)(thf)u] (1: Ln = Y, R? = Ph. n = 2: 2: Ln = Y, R? = C6H2Me32,4,6, n = 1; 3: Ln = Y, R? = tBu, n = 1: 4: Ln = Yb. R? = Ph, n = 2: 5: Ln = Lu, R? = Ph, n = 2) in high yields. These complexes, especially the yttrium complexes 1-3. serve as excellent catalyst precursors for the catalytic addition of various primary and secondary amines to carbodiimides, efficiently yielding a scries of guanidinc derivatives with a wide range of substituents on the nitrogen atoms. Functional groups such as C?N, C?CH. and aromatic C-X (X: F, Cl, Br, I) bonds can survive the catalytic reaction conditions. A primary amino group can be distinguished from a secondary one by the catalyst system, and therefore, the reaction of 1,2,3,4-tetrahydro-5-aminoisoquinoline with iPrN=C=NiPr can be achieved stepwise first at the primary amino group to selectively give the monoguanidine 38, and then at the cyclic secondary amino unit to give the biguanidine 39. Some key reaction intermediates or true catalyst species, such as the amido complexes [{Me2Si(C 5Me4)(NPh)}Y(NEt2)(thf)2] (40) and [{Me2Si(C5Me4)(NPh))Y(NHC6H 4Br4)(thf)2] (42), and the guanidinate complexes [{Me 2Si(C5Me4)(NPh)}Y{iPrNC(NEt2)(NiPr)) (thf)] (41) and [{Me2Si(C5Me4)(NPh)}Y(iPrN) C(NC6H4Br-4)(NHiPr))(thf)] (44) have been isolated and structurally characterized. Reactivity studies on these complexes suggest that the present catalytic formation of a guanidine compound proceeds mechanistically through nucleophilic addition of an amido species, formed hy acid-base reaction between a rareearth metal alkyl bond and an amine N-H bond, to a carbodiimide, followed by amine protonolysis of the resultant guanidinate species.
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Reference：
Isoxazole – Wikipedia,
Isoxazole | C3H3NO – PubChem