Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Rider, Kevin C., once mentioned the application of 638-23-3, Name is S-(Carboxymethyl)-L-cysteine, molecular formula is C5H9NO4S, molecular weight is 179.1943, MDL number is MFCD00002614, category is Isoxazoles. Now introduce a scientific discovery about this category, Recommanded Product: S-(Carboxymethyl)-L-cysteine.
Preparation of chiral isoxazole carbinols via catalytic asymmetric Corey-Bakshi-Shibata reduction
A diverse set of isoxazoles, with activity in three different disease categories, was reduced asymmetrically from pro-chiral ketones to chiral alcohols using the Corey-Bakshi-Shibata methodology at the alpha, beta, and gamma positions relative to the C-5-methyl of the isoxazole. The experiments described provide an easy route to hydroxylated isoxazoles that represent the common CYP-450 3A4 metabolic site.
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Reference:
Isoxazole – Wikipedia,
,Isoxazole | C3H3NO – PubChem